Chris Pine

This guy is about to blow up. Chris Pine has been sneaking around the back lots of Hollywood for a few years now, working his way up from The Princess Diaries 2 to the coveted role of Captain James Kirk in the upcoming Star Trek movie. His portrayal of the Cap'n is a major hot step up from the William Shatner version. Let's just hope that unlike Shatner, Chris Pine has more than Priceline.com commercials in his Captain Kirk future.